The Setup
Avi Ziskind1 asked me to cover non-commuting operators in quantum mechanics, specifically why angular momentum operators do not commute. He pointed out that Griffiths [1] gives an intuitive argument for understanding why position and momentum operators do not commute but does not present any rationale given for why the different components of angular momentum have the commutation relation
(1)
Additionally, Schwabl [2], for example, defines the angular momentum operator, presents the commutation relations, and at least attempts (I think) to show (in a post-facto way) why they should have such relations. Likewise, in a related (as we'll see) problem, Goldstein, et. al. [3] discuss the commutation relations of generators of rotation without any physical argument.However, both Sakurai [4] and Landau and Lifshitz [5], to some degree, present physical rationales for these relations. Landau and Lifshitz derive the notion of angular momentum in quantum theory quite nicely, and succinctly, but do not argue for why the commutation relations should hold. Sakurai develops a set of commutation relations independently of QM (as I will, shortly), but, I feel, bridges the gap to angular momentum rather poorly.
This post assumes familiarity with the ``generator of transformation'' ideas in [6].
The Generator of Rotation
Figure 1: The rotation of a vector around the
In a previous post I covered the notion of ``generators of transformations,''[6] and claimed, as an example, that the ``generator of rotation'' is the angular momentum. Actually, I was getting ahead of myself there, and the statement in that context was not entirely correct. As I did not derive this result in that post, I will now, and will hopefully clear things up.
Suppose we have a function
(2)
The shift in coordinates can be derived from regular vector analysis, see Fig. 1 and Ref. [7], applied inside the arguments of the function.Now the tricky part -- the Taylor expansion. Unlike the last time where the translated function had a simple
In Mathematica's notation,
The first two terms in the series give us hope. They can be written as
(4)
which are, indeed, what we would expect to see at the beginning of an exponential expansion, where Continuing with the quadratic term, let's see if we can write
(5)
which does match the mess for the Thus we conclude that
(6)
where we now identify(7)
as the generator of the rotation.This generator is the
(8)
If we carry through these same calculations for rotations around the (9)
(10)
This allows us to write the rotation operator for a rotation around an arbitrary axis (11)
where (12)
is the generator of the transformation.Commutators in general
We'd like to find a way to quantify the difference between applying the rotations in different order, but, for the sake of generality, we'll discuss this for any two arbitrary operators
(13)
is. This difference (for linear operators) does not depend on the particular vector (14)
Thus, a commutator of two operators is another operator which enacts this difference. If the order of operator application does not affect the end result the commutator is 0, and the operators are said to ``commute.''In quantum mechanics, the issue of non-commuting operators is closely tied to the problem of measurement and the uncertainty principle. For example, if I have a state
Commutators for rotation
This brings us back to our original question of the commutator of rotations. Because any two rotations through arbitrary angles, done in opposite orders give drastically different results depending on the angles, we'll consider rotations through small angles
(15)
This simpler expression makes calculating the commutator much simpler. For rotations around (16)
where 
For ease of illustration, we'll consider small rotations around the
If we start with the same vector, and apply a small rotation around
(17)
i.e. the generator of rotation around the (18)
hold for other permutations of Angular momentum
Looking back at the expression for the generator of rotations (12), we see that we can re-write this in terms of the momentum operator
(19)
in quantum mechanics:(20)
where we call (21)
In other words, the quantum mechanical angular momentum is the same (up to a constant) as the generator of rotations. Thus, the reason that quantum angular momentum has commutation relations (1) is due to the fact that it's simply a generator of rotation masquerading as a quantum mechanical operator.References
[1] D.J. Griffths. Introduction to Electrodynamics. Pearson Prentice Hall, 3rd edition, 1999.
[2] F. Schwabl. Quantum Mechanics. Springer, 3rd edition, 2005.
[3] H. Goldstein, C. Poole, and J. Safko. Classical Mechanics. Cambridge University Press, San Francisco, CA, 3rd edition, 2002.
[4] J.J. Sakurai. Modern Quantum Mechanics. Addison-Wesley, San Francisco, CA, revised edition, 1993.
[5] L.D. Landau and E.M. Lifshitz. Quantum Mechanics. Butterworth-Heinemann, Oxford, UK, 3rd edition, 1977.
[6] E. Lansey. The Schrodinger Equation -- Corrections [online]. June 2009. Available from: http://behindtheguesses.blogspot.com/2009/06/schrodinger-equation-corrections.html.
[7] D.C. Lay. Linear Algebra and Its Applications. Addison-Wesley, Reading, MA, 3rd edition, 2003.
[8] C.T.J. Dodson and T. Poston. Tensor Geometry: The Geometric Viewpoint and its Uses. Springer, 2nd edition, 1997.
1 Everyone congratulate him on the birth of a son!
2 Borrowing a joke from Dodson and Poston, [8]
3 If this isn't obvious, work it out for yourself. Hint: The identity operator 1 commutes with everything.
4 There are better arguments (see [5]) using symmetry for why