The Setup
As a first example, I'll discuss a particular pet-peeve of mine, which is something covered in many introductory quantum mechanics classes: The algebraic solution to quantum (1D) simple harmonic oscillator.1 The one-dimensional, time-independent Schrödinger equation is:
(1)
where
is the Hamiltonian of the system. Explicitly, this Hamiltonian is
(2)
where
is the particle's momentum,
is it's mass and
is the potential the particle is placed into. The potential associated with a classical harmonic oscillator is
(3)
where
. For the sake of convenience, so we don't get bogged down with various factors,2 we'll consider
. Then, if we substitute (3) back into (2) we write the Hamiltonian as:
(4)
A bad way
Figure 1: How Einstein developed his famous
expression.
Now, at this point, many texts, (see [1] or [2] for example,) define, with no motivation other than future ``convenience'', two operators
(5a)
(5b)
and proceed to show how these can be used to simplify the Hamiltonian and easily solve the problem. While it is an elegant and quick solution, this presentation is completely useless. I find it highly unlikely that Dirac sat down to solve this problem and tried a whole series of random operators
and so on, along with their complex conjugates, until he lucked out with the solution in (5), see Fig. 1.
A better way
What is far more likely is the argument given by Griffiths in [3], which I'll loosely follow. He presents a rationale and a method for approaching this problem. Namely, he suggests factoring the Hamiltonian (4) into terms linear in
and
. If we ignore the operator properties of
and
momentarily, and consider the classical quantities, we can factor the Hamiltonian
(6)
Now we see a reason why (5) makes sense to try. Each term, either on the right or left side of (6),3 contains two terms which are complex conjugates of each other. If this were a classical problem, we could, in principle, make a change of variables converting the Hamiltonian to something of the form
(7)
where
is any of the combinations of
and
in (6). Although this is not a ``canonical transformation,'' the symmetric form4 of the Hamiltonian allows us to reduce the Hamiltonian from a function of two dynamical variables to a function of a single dynamical variable.
Switching back to quantum mechanics, we now see a rationale for choosing
References
[1] J.J. Sakurai. Modern Quantum Mechanics. Addison-Wesley, San Francisco, CA, revised edition, 1993.
[2] F. Schwabl. Quantum Mechanics. Springer, 3rd edition, 2005.
[3] D.J. Griffiths. Introduction to Electrodynamics. Pearson Prentice Hall, 3rd edition, 1999.
[4] P.A.M. Dirac. The Principles of Quantum Mechanics. Oxford University Press, USA.
1 I'll be discussing this in the boring algebraic sense of symbols and whatnot, leaving off the geometric/visual interpretation of the algebra for another time.
2 Or maybe I'm just lazy
3 And, since this is a classical problem, the order does not matter, either.
4 Yes, it's only up to a constant which I've set to one, but you can still symmetrize things by changing to unitless variables, see [2].
5 Recall that the
6 It actually does not matter to the solution of the problem. The only change is which operator acts to `step up' the state. Dirac actually defined his operators with the
Although Griffith's "explanation" (also given in Peebles') as to why this ad-hoc factorisation defines the ladder operator is satisfying in an introductory course, its possible to prove rigorously why this a "correct" definition. If you look into methods developed in the context of Supersymmetric Quantum Mechanics, it can be seen that the harmonic oscillator potential is the only one which affords a Fock space description.
ReplyDeleteBut that isn't the point of the post. He wants to show how one would think to derive the operators. Of course you can prove that it is the correct definition.
ReplyDeleteThanks Anonymous - that's exactly the point. Furthermore, once you see some motivation for this 'simple' thing, you understand it a bit better; this makes the more rigorous "proofs" more meaningful, as well.
ReplyDeleteIsn't this just a case of factorizing a polynomial (a^2+b^2) using complex linear terms, while also adding an extra term which comes from the fact a, b dont commute, hence (a+ib)(a-ib) is not exactly equal to a^2+b^2. The extra term will be some multiple of the commutator [a,b]. The motivation seems clear even without the classical case.
ReplyDeleteI'll bet that you intended to cite Griffiths' Quantum Mechanics text in your References section rather than his Electrodynamics book.
ReplyDeleteActually, there is a good reason to put the i on momentum. It cancels the -i already present in the momentum operator
ReplyDeletep |psi> = -i hbar |grad psi>
That's true only in the configuration representation - which H is expressed in here, of course.
ReplyDelete